7-Isopropyl-2,9-dimethylphenanthrene and 2-Isopropyl-10-methylphenanthrene

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SYNTHESIS OF (k) - 6,8-DIHYDROXY-3- ISOPROPYL-7-METHYLISOCHROMAN

The title isochroman ( 8 ) was synthesized as a suitable substrate for acetoxylation studies leading to an intermediate of type (4), expected to afford, on condensation with diketen, the fungal metabolite "rotiorin" type linear product (1). Cyclocondensation of alcohol (6), obtained by the reduction of ketone (5) with paraform in the presence of anhydrous aluminum chloride afforded the dim...

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ژورنال

عنوان ژورنال: Bulletin of the Chemical Society of Japan

سال: 1962

ISSN: 0009-2673,1348-0634

DOI: 10.1246/bcsj.35.1970